How to manually give control of my Twitter account to my application?

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I'm dealing with 2 separate Twitter accounts.

I want to give access of my one account to my other account which holds the Twitter application/API key.

Currently it only gives the Access Token and Access Token Secret of my one account. How can I easily get this info for another account so I can tweet from both accounts via API?

asked 24 secs ago

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How to manually give control of my Twitter account to my application?